## 211. Intramolecular Site Exchange of Carbonyl Ligands in the Cluster Compounds Nonacarbonyl{p,-[q3-( 1,3,5-trithiane)])triruthenium ([ Ru,(C O),{,u ,-(q 3-C3H,S3)} I) and (tevt-But yl1socyanide)octacarbonyl-{p3-[q3-( 1,3,5-trithiane)]) triruthenium ([Ru,(t-BuNC)(CO),{p,-(q3-C,~S,)}])
Fixation of 1,3,5-Trithiane to a Trinuclear Ruthenium Framework: Synthesis, structure, and fluxionality of [Ru3(CO)6(μ2-CO)3{μ3-(η3-C3S3H6)}]
✍ Scribed by Lisa Hoferkamp; Gerd Rheinwald; Helen Stoeckli-Evans; Georg Süss-Fink
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- German
- Weight
- 316 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0018-019X
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The reactions of [Pt3R~6(CO),l(p-H)3(p3-H)] (1) with PMe3 and PPh3 have produced the salts [Pt(PR3)3H]-[Pt3R~6(CO)2,(p3-H)(p-H)2]r 5a and 5d, R = Me and Ph in the yields 9% and 22%, respectively. By contrast the reaction of 1 with PPh, in the presence of Me3N0 has yielded the phosphane-substituted d
Dedicated to Professor John R. Shapley on the occasion of his 60th birthday Considerable research effort has been devoted to preparing a variety of [60]fullerene-based (C 60 ) derivatives because of their potential application in the optical, magnetic, electronic, catalytic, and biological areas of
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