Five- and Seven-Membered Rings from Alkenyl(methoxy)carbene Complexes and Methyl Ketone Enolates
✍ Scribed by José Barluenga; Jorge Alonso; Félix Rodríguez; Francisco J. Fañanás
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 176 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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## Abstract β‐Substituted alkenylcarbene complexes react with methyl ketone lithium enolates to give different carbocyclization products depending on the structure of the lithium enolate, on the metal of the carbene complex, and on the reaction media. Thus, the reactions of aryl and alkyl methyl ke
## Abstract Fischer carbene complexes react with 4‐unsubstituted 1‐amino‐1,3‐dienes to give different carbocyclization products depending on the nature of the carbene complex and on the substitution pattern of the aminodiene. Thus, the reaction of arylcarbene chromium complexes and 1‐aminodienes di