✦ LIBER ✦

First total synthesis of (−)-8-epi-9-deoxygoniopypyrone

✍ Scribed by Jean-Philippe Surivet; Jean-Michel Vatèle

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 140 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)02269-2

No coin nor oath required. For personal study only.

✦ Synopsis

The structure and absolute configuration of natural 8-epi-9-deoxygoniopypyrone have been confirmed by an efficient and highly diastereoselective synthesis in 15 steps from (S)mandelic acid with an overall yield of 43%.

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