𝔖 Bobbio Scriptorium
✦   LIBER   ✦

First total syntheses and absolute configuration of rugulactone and 6(R)-(4′-oxopent-2′-enyl)-5,6-dihydro-2H-pyran-2-one

✍ Scribed by Debendra K. Mohapatra; Pragna P. Das; D. Sai Reddy; J.S. Yadav

Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
432 KB
Volume
50
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

rugulactone and 6(R)-(

📜 SIMILAR VOLUMES

The Stereoselective Total Synthesis of (
The Stereoselective Total Synthesis of (6S)-5,6-Dihydro-6-[(2R)-2-hydroxy-6-phenylhexyl]-2H-pyran-2-one via Prins Cyclization
✍ Jhillu Singh Yadav; Dandekar Chandrakanth; Yerragorla Gopala Rao; Kontham Ravind 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 German ⚖ 180 KB

## Abstract The stereoselective total synthesis of an antiproliferative and antifungal __α__‐pyrone natural product (6__S__)‐5,6‐dihydro‐6‐[(2__R__)‐2‐hydroxy‐6‐phenylhexyl]‐2__H__‐pyran‐2‐one is described. The key steps involved are the __Prins__ cyclization, __Mitsunobu__ reaction, and ring‐closi

Synthesis of (R)- and (R)-4-methyl-6-2′-
Synthesis of (R)- and (R)-4-methyl-6-2′-methylprop-1′-enyl-5,6-dihydro-2H-pyran (Nerol oxide) and Natural Occurrence of its Racemate
✍ Günther Ohloff; Wolfgang Giersch; Karl H. Schulte-Elte; Paul Enggist; Edouard De 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 German ⚖ 467 KB

## Abstract Following a known procedure, a mixture of (−)‐(2__S__,3__R__)‐ and (+)‐(2__R__,3__R__)‐2,3‐epoxy‐citronellols (**5**) was prepared from (−)‐(__R__)‐linalool (**3**) __via__ epoxy alcohol **4** and then reduced to (−)‐(__R__)‐3‐hydroxy‐citronellol (**6**). Sensitized photooxygenation of