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First synthesis of (−)-spongianolide A and determination of its absolute structure

✍ Scribed by Toshiyuki Hata; Katsunori Tanaka; Shigeo Katsumura

Book ID
104260837
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
223 KB
Volume
40
Category
Article
ISSN
0040-4039

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Asymmetric synthesis of putaminoxin, a phytotoxic macrolide from the cultured dinoflagellate Amphidinium sp., has been accomplished. Absolute configuration of putaminoxin was concluded to be 1 from comparison of the NMR data and [a] D values of synthetic and natural putaminoxin.