First Synthesis of 2-Vinylindole and its diels-Alder Reactions with CC-Dienophiles
✍ Scribed by Ulf Pindur; Manfred Eitel
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- German
- Weight
- 296 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0018-019X
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## Abstract The synthesis of diastereoisomeric 3,4‐disubstituted 1,2,3,4‐tetrahydrocarbazoles by Diels–Alder cycloaddition reactions between [(__E__)‐2‐vinyl]indole‐1‐carboxylic acid ethyl esters and open‐chain C=C dienophiles is reported and discussed. The reactions proceed with high regioselectiv
## Abstract For Abstract see ChemInform Abstract in Full Text.
Diels-Alder Reactions of Diaryl Thioketones with Dienophiles. -The reaction with the acetylenes (II) gives rearomatized adducts of type (III), while with (E)-cyclooctene the initial nonaromatic products (V) can be isolated.