Vinyl allenols obtained from reaction of aldehydes with vinyl propargyl bromide and indium underwent Diels-Alder reactions with a variety of symmetric and unsymmetric dieno-
Diels—Alder Reaction of Polychlorocyclopentadienes with Vinyl- and Allylacetylene Dienophiles.
✍ Scribed by M. G. Veliev; A. Z. Chalabieva; M. I. Shatirova; I. M. Mamedov; E. Sh. Mamedov
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 22 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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Diels-Alder Reactions of Diaryl Thioketones with Dienophiles. -The reaction with the acetylenes (II) gives rearomatized adducts of type (III), while with (E)-cyclooctene the initial nonaromatic products (V) can be isolated.
## Abstract For Abstract see ChemInform Abstract in Full Text.
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Vinylborane des Types A e B reagieren als Dienophile gleichermaBen rnit elektronenreichen, elektronenarmen und nicht aktivierten Dienenl-'). Sie werden deswegen als "omniphil" bezeichnet7). Folglich sollten sie auch rnit dem in Tetrazinen s-cis-fixierten Diazadiensystemio) glatt [4+2]-Cycloaddition