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First synthesis and absolute configuration of a β-farnesene-trimethoxystyrene conjugate isolated from Pachypodanthium confine

✍ Scribed by Masatsugu Koso; Takuya Tashiro; Mitsuru Sasaki; Hirosato Takikawa


Book ID
108283118
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
235 KB
Volume
65
Category
Article
ISSN
0040-4020

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Starting from (S)-malic acid and (S)-glycidol, the first total synthesis of strictifolione, a new 6-(v-phenylalkenyl)-5,6dihydro-a-pyrone isolated from Cryptocarya strictifolia, was accomplished, which confirmed its structure including the absolute configuration of the asymmetric centers.