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First structural characterization of a boron-centered radical: x-ray crystal structure of [Li(12-crown-4)2]+ [BMes3]-.bul.

✍ Scribed by Olmstead, Marilyn M.; Power, Philip P.


Book ID
125952194
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
257 KB
Volume
108
Category
Article
ISSN
0002-7863

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## Abstract An unprecedented halogen‐metal exchange was observed in the reaction between (2‐iodo‐1,3‐xylylene)‐15‐crown‐4 and diethylzinc, which resulted in the formation of (2‐iodozincio‐1,3‐xylylene)‐15‐crown‐4. An X‐ray crystal structure of this product is presented.