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A remarkable halogen-zinc exchange reaction; X-ray crystal structure of (2-iodozincio-1,3-xylylene)-15-crown-4

✍ Scribed by Gert-Jan M. Gruter; Otto S. Akkerman; Friedrich Bickelhaupt; Wilbert J. J. Smeets; Anthony L. Spek

Book ID: 104589542
Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 206 KB
Volume: 112
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19931120621

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✦ Synopsis

Abstract

An unprecedented halogen‐metal exchange was observed in the reaction between (2‐iodo‐1,3‐xylylene)‐15‐crown‐4 and diethylzinc, which resulted in the formation of (2‐iodozincio‐1,3‐xylylene)‐15‐crown‐4. An X‐ray crystal structure of this product is presented.

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