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First Stereoselective and Concise Synthesis of Rhoiptelol C

✍ Scribed by Purushotham Reddy, Sudina; Chinnababu, Baggu; Venkateswarlu, Yenamandra

Book ID
125990141
Publisher
John Wiley and Sons
Year
2014
Tongue
German
Weight
157 KB
Volume
97
Category
Article
ISSN
0018-019X

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A stereocontrolled synthesis of (-+)-geissoschizine, involving the addition of the enolate derived from l-acetylindole to pyridinium salt 2, cyclization of the resultant 1,4-dihydropyridine, stereoselective elaboration of the E-ethylidene substituent, closure of C ring by Pummerer reaction, and meth