First Rhodium/Phosphoramidite Complex-Catalyzed Enantioselective Isomerization of Allylic Alcohols into Aldehydes.
โ Scribed by Fabien Boeda; Paul Mosset; Christophe Crevisy
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 17 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
## Abstract A dicationic dichloroโbipyridineโruthenium complex shows very high catalytic activity in redox isomerization of allylic alcohols but a relatively low one in transfer hydrogenation of ketones; surprisingly, the analogous dimethylโbipyridineโruthenium complex shows reverse catalytic activ
## Abstract A Ru(II)โdichlorobipyridine complex (Ia) efficiently catalyzes the redox isomerization of terminal and internal allylic alcohols to give the corresponding ketones, e.g. (III), (V) or (VII), in high to excellent conversion.