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First oxalate-bridged dinuclear MnII-VIVO complexes: Synthesis and magnetic properties

✍ Scribed by Xian-Ru Sun; Ming-Ming Miao; Peng Cheng; Dai-Zheng Liao; Zong-Hui Jiang; Geng-Lin Wang


Book ID
103654175
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
343 KB
Volume
15
Category
Article
ISSN
0277-5387

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Three new polynuclear Mn II complexes with chloroacetate bridges were obtained and characterized by X-ray diffraction: 2), and [Mn(Β΅-ClCH 2 COO) 2 (phen)] n (3). The Mnβ€’β€’β€’Mn distance for 1 (3.624 A ˚) is smaller than for 2 (4.613 A ˚) and 3 (4.530 A ˚); this is in agreement with the number of carbox