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First heterogeneously palladium catalysed α-arylation of diethyl malonate

✍ Scribed by Laurent Djakovitch; Klaus Köhler

Book ID
108346646
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
105 KB
Volume
606
Category
Article
ISSN
0022-328X

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The influence of various heterogeneous bases on yield and selectivity in the a-arylation of diethyl malonate was studied. Barium hydroxide was found to provide excellent results in this context. The bases used can be easily removed from the reaction medium by filtration.