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First Example of Transition-Metal-Free Glaser-Type Coupling Reaction.

✍ Scribed by Jincan Yan; Lei Wang

Publisher: John Wiley and Sons
Year: 2006
Weight: 14 KB
Volume: 37
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200603055

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## Abstract Microwave‐assisted transition‐metal‐free Sonogashira‐type coupling reactions are described. The reactions are run in water as the sole solvent, without the need for copper(I) or any transition‐metal−phosphane complex. The scope of the methodology was tested by reaction of a wide variety