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First Example of Electrophile Induced Baylis—Hillman Reaction: A Novel Facile One-Pot Synthesis of Indolizine Derivatives.

✍ Scribed by Deevi Basavaiah; Anumolu Jaganmohan Rao


Book ID
101940486
Publisher
John Wiley and Sons
Year
2003
Weight
100 KB
Volume
34
Category
Article
ISSN
0931-7597

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One-pot inter- and intramolecular Friede
✍ Deevi Basavaiah; Ravi Mallikarjuna Reddy 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 67 KB

A simple one-pot stereoselective transformation of tert-butyl 3-aryl-3-hydroxy-2-methylenepropanoates, the Baylis-Hillman adducts obtained from t-butyl acrylate, into (E)-2-arylideneindan-1-ones involving one inter-and one intramolecular Friedel-Crafts reaction is described.