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One-pot inter- and intramolecular Friedel–Crafts reactions in Baylis–Hillman chemistry: a novel facile synthesis of (E)-2-arylideneindan-1-ones

✍ Scribed by Deevi Basavaiah; Ravi Mallikarjuna Reddy

Book ID: 104230425
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 67 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00354-9

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✦ Synopsis

A simple one-pot stereoselective transformation of tert-butyl 3-aryl-3-hydroxy-2-methylenepropanoates, the Baylis-Hillman adducts obtained from t-butyl acrylate, into (E)-2-arylideneindan-1-ones involving one inter-and one intramolecular Friedel-Crafts reaction is described.

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