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First example of dissymmetrical lanthanide cryptates: synthesis and steady state photophysical properties

✍ Scribed by F Bodar-Houillon; R Heck; W Bohnenkamp; A Marsura


Book ID
108344402
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
132 KB
Volume
99
Category
Article
ISSN
0022-2313

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## Abstract Three new lanthanide selenidoantimonates [Ln(en)~4~(SbSe~4~)] [Ln = La (1), Nd (2)] and [Sm(en)~4~]SbSe~4~Β·0.5en (3) (en = ethylenediamine) were first synthesized by treating LnCl~3~, Sb, and Se in a stoichiometric ratio with en under mild solvothermal conditions. Compounds 1 and 2 are