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First Asymmetric Total Syntheses and Determination of Absolute Configurations of (+)-Eudesmadiene-12,6-olide and (+)-Frullanolide

โœ Scribed by Chou, Yu-Yu; Liao, Chun-Chen


Book ID
120167231
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
491 KB
Volume
15
Category
Article
ISSN
1523-7060

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The first total synthesis of putaminoxin
โœ Gowravaram Sabitha; K. Yadagiri; R. Swapna; J.S. Yadav ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 238 KB

Asymmetric synthesis of putaminoxin, a phytotoxic macrolide from the cultured dinoflagellate Amphidinium sp., has been accomplished. Absolute configuration of putaminoxin was concluded to be 1 from comparison of the NMR data and [a] D values of synthetic and natural putaminoxin.