First Application of Chiral Ionic Liquids in Asymmetric Baylis—Hillman Reaction.
✍ Scribed by Bruce Pegot; Giang Vo-Thanh; Didier Gori; Andre Loupy
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 18 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A new kind of bifunctional (thio)urea‐phosphine catalyst was synthesized and applied to the aza‐Morita–Baylis–Hillman reaction of __N__‐sulfonated imines with methyl vinyl ketone, phenyl vinyl ketone, ethyl vinyl ketone or acrolein. Moderate to excellent __ee__ and yields of the product