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First alkylation of a 1-methoxy-substituted tricarbonyl(η5-cyclohexadienyl)iron(1 +) complex

✍ Scribed by Ian M. Palotai; G. Richard Stephenson; William J. Ross; David E. Tupper


Book ID
107811423
Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
226 KB
Volume
364
Category
Article
ISSN
0022-328X

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(η5-1-substituted-pentadienyl) (tricarbo
✍ Wlliam A. Donaldson; Muthukumar Ramaswamy 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 249 KB

The title compounds react with malonate anions by attack at both the substituted and unsubstituted terminii, to afford the trans-cis substituted diene products. (Q'-Cyclohexadienylj-and (Q5-cycloheptadienyl)iron(+ll cations are important synthetic precursors due to their regio-and stereoselective r