Fine-structure spectra and structure of N-methylporphyrins
โ Scribed by I. V. Stanishevskii; K. N. Solov'ev; S. S. Dvornikov; G. D. Egorova; E. A. Borisevich
- Publisher
- Springer US
- Year
- 1989
- Tongue
- English
- Weight
- 433 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0021-9037
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The high-resolution ( ~0.1 eV) inner valence photoelectron spectra of N2 and CO, with the binding energy in the 29-42 eV region are reported. For the first time, the effects of vibronic coupling are clearly resolved. Both spectra exhibit great complexity in structure. A preliminary assignment, based
t The terms "fine structure," "secondary absorption," "multiple absorption," etc. have been variously used in the literature to designate different regions of the structure, but because of the qualitative nature of the distinction between them and the uncertainties of interpretation these terms are