Seventeen rotational transitions up to 1L\*= 7 of the NH2 radical in its ground vibronic state have been measured by far infrared laser magnetic resonance spectroscopy. Analysis of the Zeeman patterns and hyperfine structure yrelds precise rotational, spin-rotational and distortion parameters, and i
Fine and hyperfine parameters for NH2 in X̃2B1(000)
✍ Scribed by G.W. Hills; J.M. Cook
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 355 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0022-2852
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📜 SIMILAR VOLUMES
The extended stretch-bender Hamiltonian, incorporating spin-orbit coupling and overall rotation, has been used to calculate the spin-vibronic structure of the X 2 B 1 state of NH 2 up to the barrier to linearity of this state. A detailed comparison has been made with experimental measurements of the
The stretch-bender model, developed originally to describe the effects of stretch-bend interactions and Renner-Teller coupling in symmetrical triatomic molecules, has been extended to incorporate the effects of spin-orbit interaction and of overall rotation. A comparison is made between the treatmen