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Finding the Rate-Determining Step in a Mechanism: Comparing DeDonder Relations with the “Degree of Rate Control”

✍ Scribed by Charles T Campbell

Book ID
112256616
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
77 KB
Volume
204
Category
Article
ISSN
0021-9517

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📜 SIMILAR VOLUMES

Shift of the rate-determining step in a
Shift of the rate-determining step in a consecutive chemical reaction with variation of the reaction affinity
✍ M. Enyo 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 355 KB

## Abstract A consecutive single‐route reaction is considered. When two (groups of) steps compete in controlling the overall reaction rate, there exists a general rule that the earlier step in the flow of the overall reaction tends to be rate‐determining with the increase of the reaction affinity.