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Chemistry of ylides. XXI. Mechanism of the reaction of iminophosphoranes with carbonyl compounds. Change in rate-determining step

✍ Scribed by Wong, Simon C. K.; Johnson, A. William.


Book ID
126820944
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
297 KB
Volume
37
Category
Article
ISSN
0022-3263

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Shift of the rate-determining step in a
✍ M. Enyo 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 355 KB

## Abstract A consecutive single‐route reaction is considered. When two (groups of) steps compete in controlling the overall reaction rate, there exists a general rule that the earlier step in the flow of the overall reaction tends to be rate‐determining with the increase of the reaction affinity.