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Field-dependent thermal injection into a disordered molecular insulator

✍ Scribed by Yu.N. Gartstein; E.M. Conwell


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
424 KB
Volume
255
Category
Article
ISSN
0009-2614

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✦ Synopsis


A Monte Carlo simulation is performed of emission-limited injection into an energetically disordered molecular insulator. For thermal injection, disorder leads to the increased probability for injected carriers to return to the electrode. As a result, enhanced non-linearity of the injected current is found with respect to applied electric field compared to that caused by the image force only. Particularly, the field-dependent part of the effective activation energy is significantly increased by disorder. These effects are in sharp contrast to those found for hot injected carriers.


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## Abstract Extrinsic photocurrents in anthracene and p‐chloranil crystals resulting from either electron photoemission from a metal contact or sensitized electron injection from excited adsorbed tetracene molecules are investigated. At field strengths, where space charge effects are unimportant, i