Two new polynuclear complexes of Cu II , [Cu 2 (fum)(µ-OH)(bpy) 2 (H 2 O)](NO 3 )•2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]•2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.
Ferrocene-containing chelating ligands. 1. Solution study, synthesis, crystal structure, and electronic properties of bis{N,N'-ethylenebis((ferrocenylmethyl)amine)}copper(II) nitrate
✍ Scribed by Benito, Angel; Cano, Juan; Martinez-Manez, Ramon; Soto, Juan; Paya, Jorge; Lloret, Francesc; Julve, Miguel; Faus, Juan; Marcos, M. Dolores
- Book ID
- 125482216
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 864 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0020-1669
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## Abstract The stability constants of the Cu^II^ chelates with the tripodal heptadentate ligand tris{2‐[(2‐pyridylmethyl)amino]ethyl}amine (=__N__′‐(pyridin‐2‐ylmethyl)‐__N,N__‐bis{2‐[(pyridin‐2‐ylmethyl)amino]ethyl}ethane‐1,2‐diamine; tpaa), determined by potentiometry and UV spectrometry, show t