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Direct evidence for an SN1CB mechanism. 4. Crystal and molecular structure of chloro(bis(8-quinolinyl)amido-N1,N2,N3)copper(II), a metal chelate containing an sp2-hybridized deprotonated amine

โœ Scribed by Puzas, Jeffrey P.; Nakon, Robert; Petersen, Jeffrey L.

Book ID
126949215
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
509 KB
Volume
25
Category
Article
ISSN
0020-1669

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Direct evidence for an SN1CB mechanism.
Direct evidence for an SN1CB mechanism. 4. Crystal and molecular structure of chloro(bis(8-quinolinyl)amido-N1,N2,N3)copper(II), a metal chelate containing an sp2-hybridized deprotonated amine
โœ Puzas, Jeffrey P.; Nakon, Robert; Petersen, Jeffrey L. ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 509 KB

where an exothermic reaction occurred. After 1 h at 25 "C, all volatile materials were evacuated to leave a white solid, CF3CH,0Li (20 mmol, Preparation of 2,2,2-Trifluoroethyl Dichlorophosphinite, CF3CH20P-CI2. Onto CF,CH,OLi (20 mmol, 2.1 g) in a 1000-mL round-bottomed Pyrex flask at -196 OC, was