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Ferrocene and Pentaphosphaferrocene: A Comparative Study Regarding Redox Chemistry

✍ Scribed by Butovskiy, Mikhail V.; Balázs, Gábor; Bodensteiner, Michael; Peresypkina, Eugenia V.; Virovets, Alexander V.; Sutter, Jörg; Scheer, Manfred

Book ID
120336236
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
454 KB
Volume
52
Category
Article
ISSN
0044-8249

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The doubly boron-bridged diferrocene [CpFe{C 5 H 3 (BPh) 2 C 5 H 3 }FeCp] represents the first example of a 1,2-diborylated ferrocene. Controlled conformational changes in this rigid redox-active bifunctional Lewis acid species can be triggered either through redox chemistry or the binding of nucleo