Fermi resonance in the carbonyl band of cyclopentanone
β Scribed by R. E. Davis; Kwang Sup Kim
- Publisher
- Springer
- Year
- 1972
- Tongue
- English
- Weight
- 301 KB
- Volume
- 25
- Category
- Article
- ISSN
- 1432-2234
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We have observed microwave-driven inversion and recovery of the populations of the spin SUblcVelS of the chemically reactive, IIT\* triplet state ofcyclopentanone at 77,4.2, and 1.4"K. By analyzing the transients in the phosphorescence, we have extracted the values of the kinetic parameters for the
Fine structure and hyperfine structure information on the chemically reactive 3n~t state of cyclopentanone is obtained by the low field microwave-optical double resonance (MODOR) technique. The hvperfine structure is interpreted ter.tatively to indicate rtit the nxsnetic z asis lies perpendicular to