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Fermentative Verarbeitung von Stärkeabfällen zu Butanol und Aceton

✍ Scribed by Dr. Abbas Scharif Afschar; Dr. Hanno Biebl; Konrad Schaller


Publisher
John Wiley and Sons
Year
1987
Tongue
German
Weight
147 KB
Volume
59
Category
Article
ISSN
0009-286X

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Katalytische Carbonylierung von Aceton-o
✍ Meinhard Langenbahn; Helen Stoeckli-Evans; Georg Süss-Fink 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 German ⚖ 312 KB

In the presence of catalytic amounts of [Ru,(CO),(Me2CNO)2(Me2CNOH)2] (l), acetone oxime reacts with carbon monoxide to give 2,3,4,5-tetrahydro-2,2,4,4,6-pentamethylpyrimidine ('acetonine'), CO,, and NH,. The reaction proceeds presumably via carbonylation of Me,C=NOH to the unstable intermediate Me,