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Fenton's reagent. IV. Structure and reactivity relations in the reactions of hydroxyl radicals and the redox reactions of radicals

✍ Scribed by Walling, Cheves; El-Taliawi, Gamil M.; Johnson, Richard A.

Book ID: 121860291
Publisher: American Chemical Society
Year: 1974
Tongue: English
Weight: 836 KB
Volume: 96
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00808a022

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The reactions of HI with OH and NO3 have been studied in discharge-flow reactors coupled to EPR and mass spectrometry for analysis, The rate constants for the reactions HI+OH+H20 t I (1) and HI t NO3 +HNO, t I (2) were determined al 298 K: k,=(3.3+0.2)xlO-" and kz = (2.5f0.8) X 10 --IS cm3 molecule-