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Femtosecond Dynamics of a Hydrogen-Bonded Model Base Pair in the Condensed Phase: Double Proton Transfer in 7-Azaindole

✍ Scribed by Chachisvilis, M.; Fiebig, T.; Douhal, A.; Zewail, A. H.

Book ID: 121334467
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 81 KB
Volume: 102
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp980337b

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The results of spectral and photophysical studies strongly suggest that photoinduced proton transfer in 7-(2-pyridyl)indole (1) is accompanied by mutual twisting of the pyridyl and indole moieties. This conclusion is supported by the unusual finding that the photoreaction is faster in a cold, supers