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Proton transfer with a twist? Femtosecond Dynamics of 7-(2-pyridyl)indole in Condensed Phase and in Supersonic Jets

✍ Scribed by Y. Nosenko; G. Wiosna-Sałyga; M. Kunitski; I. Petkova; A. Singh; W. J. Buma; R. P. Thummel; B. Brutschy; J. Waluk


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
384 KB
Volume
120
Category
Article
ISSN
0044-8249

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Proton transfer with a twist? Femtosecon
✍ Y. Nosenko; G. Wiosna-Sałyga; M. Kunitski; I. Petkova; A. Singh; W. J. Buma; R.  📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 384 KB 👁 2 views

The results of spectral and photophysical studies strongly suggest that photoinduced proton transfer in 7-(2-pyridyl)indole (1) is accompanied by mutual twisting of the pyridyl and indole moieties. This conclusion is supported by the unusual finding that the photoreaction is faster in a cold, supers