Fe(I)-Mediated Regio- and Stereoselective CC/CH Bond Activation of Internal Methylene Groups of α,ω-Diphenylalkanes

Geminal-Dialkyl-Effect-Controlled Site S

Geminal-Dialkyl-Effect-Controlled Site Selectivity of Fe(I)-Mediated C  H/C  C Bond Activation of Aliphatic Ketones

✍ Schröder, Detlef ;Bowie, John H. ;Stringer, M. B. ;Schwarz, Helmut 📂 Article 📅 1991 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 179 KB

Bond activation, C -H, C -C / Transition-metal ions / Tandem mass spectrometry / Geminal dialkyl effect Depending on the internal energy content, due to the operation of a geminal dialkyl effect, the Fe+-mediated dehydro-genation of a,a-dimethyl-substituted ketones preferably involves the more subst