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Features of reactions of 10-methyl-9,10-dihydroacridine heteroanalogs with imines

✍ Scribed by L. P. Yunnikova; T. V. Makhova; A. L. Yunnikov; V. Yu. Gorokhov

Book ID
111465028
Publisher
SP MAIK Nauka/Interperiodica
Year
2009
Tongue
English
Weight
349 KB
Volume
45
Category
Article
ISSN
1070-4280

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## Abstract Hydrogen is transferred from acridane (1c) and __N__‐methylacridane (1d) to α‐methyl‐styrene (2) in a bimolecular uncatalyzed reaction at 260–300Β°C. On the basis of the activation parameters (for 1c: Ξ”__H__^β‰ ^ = 29.0 kcal/mol, Ξ”__S__^β‰ ^ = βˆ’23.5 e.u. in triglyme) the kinetic isotope effe