Fast ion transport in the NASICON analog Na3Sc2(PO4)3: Structure and conductivity
โ Scribed by S. Susman; C.J. Delbecq; T.O. Brun; E. Prince
- Book ID
- 107914049
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 516 KB
- Volume
- 9-10
- Category
- Article
- ISSN
- 0167-2738
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๐ SIMILAR VOLUMES
The ~tal m~u~ of the thee c~t~] t~ of~hr SC NAStCON an~l~ a~ in~e~i~t~ b=l~ r~ ~0 s~d 60O ~ A ~s~tlc ~p~ey of Ihr mld-Na silr is ~nd ex~pl in the I~lem~t u~ p~sr ort~ 0 t~ '~qlh ~n~a~ing tem~tu~ ,~ is ~ tra~f~ U~ Na( I ) into mi~.Na sites, whereas t~ N~( 2 ) si~ ~tai~s a ~n~t~t o~u~aacy of 2 ~ u~it
From experimental data on impedance, IR, Raman and nuclear magnetic resonance spectroscopy it is shown that each lithium ion moves by "classical" hopping in Li3Sc2(PO4) 3 superionic crystals, i.e. the residence time rr is much greater than the time rf of flight. At the same time the charge transfer