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Fast formation of the hydrated electron by dissociation of excited β-naphtholate

✍ Scribed by Chmouel R. Goldschmidt; Gabriel Stein

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
393 KB
Volume
6
Category
Article
ISSN
0009-2614

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✦ Synopsis

Excitation to the lowest singlet state of &naphtholate ion in aqueous solution, @y the ahsorptirm of the 3371A light from a 7 nsec pulse of an N laser) is followed within61 nsec by formation of a hydrated electron, e&. This process precedes the ormation of the fluorescent excited state and competes with it.

H Increased temperature increases eiq formation and decreases fluorescence.

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