The mass spectrometric behaviour of six Schiff bases derived from the condensation in acetonitrile or methanol of ferrocenecarboxaldehyde with polyamines H,N-R-NHz (R =-H,C-CHz-9-CHz-CHr, -HzC-CH,-, -HzC--CHrN[(CH2 ),,-CH3]-CHZ-CHz-, -(HzC)&,H8Nr(CHz)~) has been investigated by fast atom bombardment
Fast atom bombardment mass spectrometry of new polydentate schiff bases. 2. The case of mono- and bisaldimines containing pyridine groups
✍ Scribed by M. Coppola; S. Catinella; P. Traldi; P. Guerriero; S. Tamburini; P. A. Vigato
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 393 KB
- Volume
- 29
- Category
- Article
- ISSN
- 1076-5174
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✦ Synopsis
Abstract
The mass spectrometric behaviour of seven polydentate Schiff bases derived from the condensation of formyl or diformyl precursors (2,3‐dihydroxy‐ or 2,5‐dihydroxy‐benzaldehyde, 3‐metoxy‐ or 3‐ethoxy‐salicylaldehyde, 3‐formyl‐salicyclic acid, 4‐methoxy‐ or 4‐chloro‐2,6‐diformylphenol) with 2‐aminomethylpyridine have been investigated by fast atom bombardment mass spectrometry and metastable ion studies.
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Four macrocyclic tetraimine Schiff bases containing oxamidic groups were synthesized by [2 + 2] condensation of N,N'-bis(2-aminoethyl)oxamide or N,N'-bis(2-amino-1,1-dimethylethyl)oxamide with 2,6-diformyl-4chlorophenol or 2,6-diformyl-4-methylphenol and characterized by elemental analyses and IR an