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Fast Atom Bombardment Mass Spectrometry of New Polydentate Schiff Bases. 4. The Case of bis-Aldimines Containing Ferrocene Groups

✍ Scribed by Elvio Bullita; Sergio Tamburini; Pietro Alessandro Vigato; Massimo Carbini; Silvia Catinella; Pietro Traldi

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 323 KB
Volume: 10
Category: Article
ISSN: 0951-4198
DOI: 10.1002/(sici)1097-0231(19960331)10:5<490::aid-rcm507>3.0.co;2-j

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✦ Synopsis

The mass spectrometric behaviour of six Schiff bases derived from the condensation in acetonitrile or methanol of ferrocenecarboxaldehyde with polyamines H,N-R-NHz (R =-H,C-CHz-9-CHz-CHr, -HzC-CH,-, -HzC--CHrN[(CH2 ),,-CH3]-CHZ-CHz-, -(HzC)&,H8Nr(CHz)~) has been investigated by fast atom bombardment mass spectrometry and metastable ion studies. When oxygen and sulfur atoms are present in the ehaln, extensive fragmentation processes are observed, while the presence of nitrogen atoms leads to a more stable molecular species.

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