The potential of positive and negative ion fast atom bombardment mass spectrometry in the examination of cyanogenic glycosides has been demonstrated by the analysis o f linamarin, prunasin, neolinustatin and amygdalin.
Fast atom bombardment mass spectrometry of elymoclavine glycosides
✍ Scribed by Vladimír Havliček; Miroslav Flieger; Vladimír Křen; Miroslav Ryska
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 359 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1076-5174
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✦ Synopsis
A series of nine naturally occurring and/or semi-synthetic elymoclavine mono-and oligoglycosides containing various sugar units was investigated by fast atom bombardment, high-resolution measurements and linked scans. The fragmentations of the [M + H] + and [M + N a ] + ions are described and their difFerent contributions to the structure elucidation are discussed.
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Three glutathione conjugates of acetaminophen were characterized by fast atom bombardmentlmass spectrometry (FABlMS) and fast atom bombardmentlmass spectrometryhass spectrometry (FABlMSlMS). The conjugates, 3-(glutathion-S-yl)acetaminophen, 3-(glutathion-S-yl)diacetaminophen and 3-(diglutathion-S-yl