Far infrared investigation of the rotational motion of CHClF2 and CH3F at high pressures and temperatures
β Scribed by M.A. Bohn; M. Frost; E.U. Franck
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 217 KB
- Volume
- 139-140
- Category
- Article
- ISSN
- 0378-4363
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π SIMILAR VOLUMES
Atomic resonance absorption spectrometry with a nonreversed fluorine resonance lamp (-95 nm) has been used to study the kinetics of elementary reactions of ground state F2Pj atoms in a discharge-flow system. The following rate constants (in cm3/rnolec.sec)\*\* were determined a t 298Β°K: (1)
## Abstract Rate constants are calculated for CH~3~ (+ Ar) β CH~2~ + H (+ Ar) at the limiting lowβpressure, the limiting highβpressure, as well as the intermediate fallβoff ranges. The results show that published experimental rate constants for methyl dissociation correspond to the fallβoff region