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Kinetics of fluorine atom reactions using resonance absorption spectrometry in the far vacuum ultraviolet reactions F + HCl, CH4, CHCl3 CHCl2F, and CHClF2

โœ Scribed by Michael A. A. Clyne; Wing S. Nip

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
786 KB
Volume
10
Category
Article
ISSN
0538-8066

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โœฆ Synopsis

Atomic resonance absorption spectrometry with a nonreversed fluorine resonance lamp (-95 nm) has been used to study the kinetics of elementary reactions of ground state F2Pj atoms in a discharge-flow system. The following rate constants (in cm3/rnolec.sec)** were determined a t 298ยฐK:

(1)

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A kinetic study of the reaction of fluor
A kinetic study of the reaction of fluorine atoms with CH3F, CH3Cl, CH3Br, CF2H2, CO, CF3H, CF3CHCl2, CF3CH2F, CHF2CHF2, CF2ClCH3, CHF2CH3, and CF3CF2H at 295 ยฑ 2 K
โœ Timothy J. Wallington; Michael D. Hurley; Jichun Shi; M. Matti Maricq; Jens Sehe ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 807 KB

A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.