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Factors Influencing the Formation of Medicinal Off-Flavor from Ascorbic Acid and α,β-Unsaturated Aldehydes

✍ Scribed by Sakamaki, Kensuke; Ishizaki, Susumu; Ohkubo, Yasutaka; Fujimoto, Hiroshi; Fujita, Akira


Book ID
118176492
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
585 KB
Volume
60
Category
Article
ISSN
0021-8561

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Chiral α-hydroxy- and α,β-dihydroxy- ald
✍ Y Le Merrer; C Gravier-Pelletier; J Dumas; J.C Depezay 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 273 KB

&mm6fy : The four possible stereoisomers of a$dihydroxyaldehydes, useful building blocks for the synthesis of fatty acids metabolites, are synthesized via epoxy-tetrols derived from D-isoascorbic and L-ascorbic acids. The general method we develop allows the synthesis of chiral a-hydroxyaldehydes as