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Chiral α-hydroxy- and α,β-dihydroxy- aldehydes from D-isoascorbic and L-ascorbic acids. Useful precursors for the synthesis of fatty acid metabolites.

✍ Scribed by Y Le Merrer; C Gravier-Pelletier; J Dumas; J.C Depezay

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
273 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

&mm6fy : The four possible stereoisomers of a$dihydroxyaldehydes, useful building blocks for the synthesis of fatty acids metabolites, are synthesized via epoxy-tetrols derived from D-isoascorbic and L-ascorbic acids. The general method we develop allows the synthesis of chiral a-hydroxyaldehydes as well.

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