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Factors influencing stereochemistry in the reduction of conformationally mobile 2-alkylcyclohexanones by sodium borohydride

✍ Scribed by Wigfield, Donald C.; Phelps, David J.

Book ID: 126076285
Publisher: American Chemical Society
Year: 1974
Tongue: English
Weight: 868 KB
Volume: 96
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00809a034

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## Abstract The reduction of different 2‐azolyl‐and azinylisoquinolinium salts with sodium borohydride in methanol was studied. Surprisingly, contrary to what is found in the literature 1,2‐dihydroisoquinoline derivatives were obtained. Their formation was attributed to the electron withdrawing cha