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Factor group splitting in the lowest triplet state of p-benzoquinone-d4 crystals

✍ Scribed by Hendrik Veenvliet; Douwe A. Wiersma

Publisher: Elsevier Science
Year: 1975
Tongue: English
Weight: 361 KB
Volume: 33
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(75)80162-x

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✦ Synopsis

Polzrizec! Stark-modulated Zceman absorption experiments on p-benzoquinonedc single crystds at 2 Ii show the fzctoi goup sp!itting in the origin of the lowest Big (n;;*) rrip1e.t state at 1854s cinvl io lx 0.6ZO.06

cm-', Tine ordering OF the crystal states is such that the orbitd p!us skte ties at higher energy. 'ihe absence of a me2sUrable i2CtOr gKWp SO!itring in *be 'Au (n;;*) state at 13.1 cmei from the origin is aken BS 2 further confiimn-tion of tile Gbroric nature of this stzte. The 2F.S parameterD of this level is found to be -lo+3 GHz.

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