✦ LIBER ✦

Facile synthesis of α-hydroxy carbonyl compounds by enolate oxidation with dimethyldioxirane

✍ Scribed by Kevin R. Guertin; Tak-Hang Chan

Publisher: Elsevier Science
Year: 1991
Tongue: French
Weight: 289 KB
Volume: 32
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)74865-9

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✦ Synopsis

The dwzt oxldatron of enolates with &methylchoxirane ( as a solunon m acetone ) provides the ahydroxy &nvanves m excellent yield

The converSlon of enohzable ketones to their correspondmg a-hydroxy denvatlves 1s an important synthenc transformanon and has received a great deal of attennon la2 The class~al method of acluevmg tis transformation

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