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Facile synthesis of acetylenecarboxylates by the oxidative carbonylation of terminal acetylenes catalyzed by PdCl2 under mild conditions

✍ Scribed by Jiro Tsuji; Mitsuo Takahashi; Takashi Takahashi

Book ID: 104213112
Publisher: Elsevier Science
Year: 1980
Tongue: French
Weight: 129 KB
Volume: 21
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)71522-x

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✦ Synopsis

Terminal acetylenes were converted to acetylenecarboxylates in high yields under atmospheric pressure of carbon monoxide at room temperature using a catalytic amount of PdC12 and a stoichiometric amount of CuC12.

Considerable studies have been carried out on the palladium-catalyzed carbonylation of acetylenic compounds to give a,B-unsaturated mono-and diesters,

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