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Facile Synthesis of 4-Functionalized Cyclopentenones.

✍ Scribed by Sujit Kumar Ghorai; Nirmal Kumar Hazra; Dipakranjan Mal

Publisher
John Wiley and Sons
Year
2007
Weight
21 KB
Volume
38
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Facile synthesis of 2-substituted cyclop
Facile synthesis of 2-substituted cyclopentenones
✍ S.W. Baldwin; H.R. Blomquist Jr. πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 218 KB

## Summare An efflclent synthesis of 2-substituted cyclopentenones IS reported Key reactions are the cylopropanatlon of 2,2-dlmethyl-3(2H)-f uranone and subsequent conversion to the title compounds by oxldatlve fragmentation.

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A general route to functionalized catechols is achieved by the reaction of 3,6-di(chloromethyl)-4,5dimethyl-catechol with various nucleophiles in the presence of a base. The reactions are proposed to occur by way of a dehydrochlorinated intermediate which undergoes Michael additions to give the cate